Bezpečnostný list Lofrix Original

*Dostupné len v angličtine*

SAFETY DATA SHEET

Lofrix Original

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2020/878

1.1 Product identifier

Product name

Lofrix Original

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified Use(s)

PC24 Lubricants, greases, release products-in  concentrations of 1-3% of the volume of lubrication oil in the system to be treated.

Uses Advised Against 

Not known.

1.3 Details of the supplier of the safety data sheet

Company Identification

Lofrix Associates Ltd

Address of Supplier

10 Park Place 

Manchester, United Kingdom

Postal code

M4 4EY

Telephone

0161 969 9195

E-mail

info@lofrix.com, ians@lofrix.com

Office hours

08:00 - 17:00

1.4 Emergency telephone number

Company

0161 969 9195

National response centre (NHS Direct)

+44 111

2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008 (CLP)

Lact :May cause harm to breast-fed children.

Aquatic Acute 1 :Very toxic to aquatic life.

Aquatic Chronic 1 :Very toxic to aquatic life with long lasting effects.

2.2 Label elements

According to regulation (EC) No. 1272/2008 (CLP)

Product name

Lofrix Original

Hazard Pictogram(s)

GHS09

Signal Word(s)

Warning

Hazard Statement(s)

H362: May cause harm to breast fed children

H410: Very toxic to aquatic life with long lasting effects.

EUH066: Repeated exposure may cause skin dryness or cracking.

EUH208: Contains: cycloaliphatic epoxy resin. May produce an allergic reaction.

Precautionary Statement(s)

P201: Obtain special instructions before use.

P263: Avoid contact during pregnancy and while nursing.

P273: Avoid release into the environment.

P308+P313: IF exposed or concerned: Get medical advice/attention.

P391: Collect spillage.

P501: Dispose of contents in accordance with local, state or national legislation.

2.3 Other hazards                                                                                                                   None known.

2.4 Additional Information                                                                                                    For full text of H/P Statements see section 16.

3.1 Substances                                                                                                                        Not applicable.

3.2 Mixtures

Contains no non-classified vPvB substances. Contains no non-classified substances with a Union workplace exposure limit. For full text of H/P Statements see section 16

4.1 Description of first aid measures

Inhalation

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

Skin Contact

Remove contaminated clothing. Wash all affected skin with soap and water.

Eye Contact

Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes.

Ingestion

Wash out mouth with water and give 200-300 ml (half a pint) of water to drink.

4.2 Most important symptoms and effects, both acute and delayed                                May cause harm to breast-fed children.

4.3 Indication of any immediate medical attention and special treatment needed        IF exposed or concerned: Get medical advice/attention.

5.1 Extinguishing media

Suitable Extinguishing media

As appropriate for surrounding fire.

Unsuitable Extinguishing media

None.

5.2 Special hazards arising from the substance or mixture                                                Non-flammable: May decompose if heated above 200°C with liberation of hydrogen chloride.

5.3 Advice for firefighters                                                                                                      Firefighters should wear complete protective clothing including self-contained breathing apparatus. Dike fire control for later disposal.

6.1 Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation. Do not breathe vapour. Wear appropriate personal protective equipment, avoid direct contact.

6.2 Environmental precautions

Avoid release into the environment. Spillages or uncontrolled discharges into watercourses must be altered to the appropriate regulatory body.

6.3 Methods and material for containment and cleaning up

Absorb spillages onto sand, earth or any suitable absorbent material. Collect spillage. Transfer to a container for disposal or recovery.

6.4 Reference to other sections

See Also Section 8,13.

7.1 Precautions for safe handling

Obtain special instructions before use. Avoid contact during pregnancy and while nursing. Provide adequate ventilation. Do not breathe vapour. Wash hands and exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed.

Storage temperature

Ambient. Recommended: <40°C

Storage life

Stable under normal conditions.

Incompatible materials

Strong oxidising agents, Acids.

7.3 Specific end use(s)

PC24 Lubricants, greases, release products - in concentrations of 1-3% of the volume of lubrication oil in the system to be treated.

8.1 Control parameters

8.1.1 Occupational Exposure Limits

Source: UK Workplace Exposure Limits EH40/2005 (Forth edition, published 2020), United Kingdom

8.2 Exposure controls

8.2.1 Appropriate engineering controls

Provide adequate ventilation. The floor of the storage room must be impermeable to prevent the escape of liquids.

Eye Protection

Wear protective eye glasses for protection against liquid splashes

Skin Protection

Wear suitable gloves if prolonged skin contact is likely. Breakthrough time of the glove material: refer to the information provided by the gloves producer.

Respiratory protection

A suitable mask with filter type A (EN14387 or EN405) may be appropriate

Thermal hazards

N/A

8.2.3 Environmental Exposure Controls 

9.1 Information on basic physical and chemical properties

Physical state

Liquid.

Colour

Amber.

Odour

Almost odourless.

Melting point/freezing point

Not known.

Boiling point or initial boiling point and boiling range

>200°C

Flammability

Non-flammable.

Lower and upper explosion limit

Not known.

Flash point

200°C @ 1013 hPa (Alkanes, C14-17, chloro)

Auto-ignition temperature

Not known.

Decomposition temperature

Not known.

pH

Not known.

Kinematic Viscosity

Viscous. 25-1200 mm2/s @ 40°C (Alkanes, C14-17, chloro)

Solubility

Solubility (Water) : Insoluble. 0.027 mg/l @ 20°C (Alkanes, C14-17, chloro) 

Solubility (Other) : Most organic solvents

Partition coefficient n-octanol/water (log value)

Log Kow (Pow): 7 @ 20°C (Alkanes, C14-17, chloro)

Vapour pressure

Practically non-volatile. 0.00027 Pa @ 20°C (Alkanes, C14-17, chloro)

Density and/or relative density

1.32 (typically)

Relative vapour density

Not known.

Particle characteristics

Not applicable.

9.2 Other information

Oxidising properties

Not oxidising.

10.1 Reactivity

None anticipated.

10.2 Chemical Stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose. Can react with alkali metals and alkaline earth metals which have a strong affinity of chlorine. Can react with iron, zinc and aluminium at high temperatures leading to decomposition.

10.4 Conditions to avoid

Heat and direct sunlight.

10.5 Incompatible materials

Strong oxidising agents, Acids.

10.6 Hazardous decomposition products

Prolonged heating at temperatures in excess of 70°C or heating above 200°C for short periods of time will result in decomposition and liberation or hydrogen chloride.

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity

Calculation method: Not classified.

Low oral toxicity.

Alkanes, C14-17, chloro: LD50 (oral,rat) mg/kg > 2000

Skin corrosion/irritation

Calculation method: Not classified.

Repeated exposure may cause skin dryness or cracking.

Alkanes, C14-17, chloro: slight skin irritation reported in two studies conducted according to OECD Guideline 404 using undilute C14-17 chlorinated paraffins (40 & 52% chlorination - containing 1% epoxy stabiliser).

Serious eye damage/irritation

Calculation method: Not classified.

Alkanes, C14-17, chloro: slight eye irritation reported in two studies conducted according to OECD Guideline 405 using undilute C14-17 chlorinated paraffins (40 & 52% chlorination - containing 1% epoxy stabiliser).

Skin sensitization data

Calculation method: Not classified.

It is not a skin sensitiser.

Respiratory sensitization data

Calculation method: Not classified.

Germ cell mutagenicity

Calculation method: Not classified.

Alkanes, C14-17, chloro: Not mutagenic to bacteria or in in-vivo mouse bone marrow micronucleus assays.

Carcinogenicity 

Calculation method: Not classified. No evidence of carcinogenic effects. Alkanes, C14-17, chloro: Chlorinated paraffins, as a group of chemicals are not genotoxic. Their lack of genotoxic activity together with the results of other studies leads us to conclude that chlorinated paraffins are unlikely to present a carcinogenic hazard to man under normal conditions of handling and use.

Reproductive toxicity

Calculation method: Not classified. No evidence of reproductive effects. No reported effects on fertility at doses up to 400 mg/kg/day. Alkanes, C14-17, chloro: No effects in conventional development toxicity studies with doses up to 5000 mg/kg/day (rat) and 100 mg/kg/day (rabbit). Mortality due to internal haemorrhaging has been seen in new-born rats, reared by dams fed on high doses of a similar chlorinated paraffin.

Lactation

Calculation method: may cause harm to breast-fed children. No data.

STOT - single exposure

Calculation method: Not classified.

STOT - repeated exposure

Calculation method: Not classified.

Aspiration hazard

Calculation method: Not classified.

11.2 Information on other hazards

Not known.

12.1 Toxicity 

Very toxic to aquatic life with long lasting effects. Alkanes, C14-17, chloro: LC50 (96 hour) > 5000 mg/l

12.2 Persistence and degradability

The product is not biodegradable.

12.3 Bio accumulative potential

The product has potential for bioaccumulation.

12.4 Mobility in soil

Insoluble in water. The product is predicted to have low mobility in soil.

12.5 Results of PBT and vPvB assessment

Not classified as PBT or vPvB.

12.6 Endocrine disrupting properties

None anticipated.

12.7 Other adverse effects

Not known.

13.1 Waste treatment methods

Dispose of contents/container to: approved waste disposal facility.

13.2 Additional Information

Disposal should be in accordance with local, stat or national legislation.

14.1 Un number or ID number

UN No.

3082

14.2 UN proper shipping name

UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains: Alkanes, C14-17 chloro)

14.3 Transport hazard class(es)

ADR/RID

ADR/RID Class

9

ADR Classification Code

M6

Special Provisions

274 335 375 601

Limited Quantities

5 L

Excepted Quantities

E1

Emergency Action Code

• 3Z

Mixed Packing Instructions for Packages

P001 IBC03 LP01 R001

Mixed Packing Provisions for Packages

PP1

Mixed Packing Instructions for Packages

MP19

Packing Instructions for Portable Tanks

T4

Special Provisions for Portable Tanks

TP1 TP29

Tank Code for Tanks

LGBV

Vehicle for Tank Carriage

AT

ADR Transport Category

3

Tunnel Restriction Code

-

Special Provisions for Carriage - Packages

V12

Special Provisions for Carriage - Loading, Unloading and Handling

CV13

ADR HIN

90

IMDG Class

9

Special Provisions

274 335 375 601

Limited Quantities 

5 L

Excepted Quantities

E1

Mixed Packing Instructions for Packages

P001 IBC03 LP01 R001

Special Packaging Provisions for Packages

PP1

Packing Instructions for Portable Tanks

T4

Special Provisions for Portable Tanks

TP1 TP29

IMDG EMS

F-A-S-F

Stowage and Handling

category A

ICAO/IATA

IATA Proper Shipping Name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains: Alkanes, C14-17, chloro)

Excepted Quantities

E1

Passenger and Cargo Aircraft Limited Quantities Packing Instructions

Y964

Passenger and Cargo Aircraft Limited Quantities Max net Qty

30Kg G

Passenger and Cargo Aircraft Max net Qty

964

Passenger and Cargo Aircraft Max net Qty

450L

Cargo Aircraft Packing Instructions

964

Cargo Aircraft Max net Qty

450L

Special Provisions

A97, A158, A197, A215

Emergency Response Guidebook (ERG)

9L

Code 

9

Labels

14.4 Packing group

Packing group

III

14.5 Environmental hazards

Environmental hazards

Classified as a Marine Pollutant.

14.6 Special precautions for user

Special precautions for user

Not known.

14.7 Maritime transport in bulk according to IMO instruments

Ship Type: 1

Pollution Category: X

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

European Regulations - Authorisation and/or Restrictions On Use

Candidate List of Substances of Very High Concern for Authorisation 

Alkanes, C14-17, chloro (85535-85-9)

REACH: Annex XIV list of substances subject to authorisation

Not listed

REACH: Annex XVII Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

Alkanes, C14-17, chloro (85535-85-9)

Community Rolling Action Plan (CoRAP)

Alkanes, C14-17, chloro (85535-85-9)

Regulation (EU) N° 2019/1021 of the European Parliament and of the Council on persistent organic pollutants

Not listed

Regulation (EU) N° 1005/2009 on substances that deplete the ozone layer

Not listed

Regulation (EU) N° 649/2012 of the European Parliament and of the Council concerning the export and import of hazardous chemicals

Not listed

National regulations

None.

15.2 Chemical Safety Assessment

Not applicable.

The following sections contain revisions or new statements: 2,3,9,11,14,15,16

LEGEND

Hazard Pictogram(s)

GHS09

Hazard classification

Lact. : Lactation

Aquatic Acute 1: Hazardous to the aquatic environment, Acute, Category 1

Aquatic Chronic 1: Hazardous to the aquatic environment, Chronic, Category 1

Hazard Statement(s)

H362: May cause harm to breast fed children.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

EUH066: Repeated exposure may cause skin dryness or cracking.

EUH208: Contains: cycloaliphatic epoxy resin. May produce an allergic reaction.

Precautionary Statements(s)

P201: Obtain special instructions before use.

P260: Do not breathe vapour.

P263: Avoid contact during pregnancy and while nursing.

P264: Wash hands and exposed skin thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P273: Avoid release into the environment.

P308+P313: IF exposed or concerned: Get medical advice/attention.

P391: Collect spillage.

P501: Dispose of contents in accordance with local, state or national legislation.

Acronyms

ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways.

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.

CAS: Chemical Abstract Service.

CLP: Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.

DNEL: Derived No Effect Level.

EC: European Community.

EINECS: European Inventory of Existing Commercial Chemical Substances.

IATA: International Air Transport Association.

IBC: Intermediate Bulk Container.

ICAO: International Civil Aviation Organisation.

IMDG: International Maritime Dangerous Goods.

LTEL: Long term exposure limit.

PBT: Persistent, Bioaccumulative and Toxic.

PNEC: Predicted No Effect Concentration.

REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals.

RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.

STEL: Short term exposure limit.

STOT: Specific Target Organ Toxicity.

UN: United Nations.

vPvB: very Persistent and very Bioaccumulative.

Key literature references and sources for data used to compile the SDS

Regulation (EC) No. 1272/2008 (CLP)

Upozornenia

Informácie uvedené v tejto publikácii alebo inak poskytnuté používateľom sa považujú za presné a sú poskytované v dobrej viere. Je však na používateľoch, aby sa sami uistili o vhodnosti produktu pre ich vlastné konkrétne účely.

Lofrix Associated Ltd neposkytuje žiadnu záruku ani podmienku (zákonnú alebo inú), okrem prípadu, keď zákon takúto výnimku neumožňuje.

Lofrix Associated Ltd nenesie žiadnu zodpovednosť za stratu alebo škodu (okrem tých, ktoré vzniknú v dôsledku úmrtia alebo zranenia spôsobeného chybným výrobkom, ak sa to preukáže), ktoré by vyplynuli zo spoliehania sa na tieto informácie. Nemožno predpokladať žiadne práva vyplývajúce z patentov, autorských práv alebo dizajnov.